Butyl group In organic chemistry , butyl is a four-carbon alkyl radical or substituent group with general chemical formula −C4 H9 , derived from either of the two isomers of butane . The isomer n -butane can connect in two ways, giving rise to two "-butyl" groups: If it connects at one of the two terminal carbon atoms , it is normal butyl or n-butyl: CH3 −CH2 −CH2 −CH2 − If it connects at one of the non-terminal carbon atoms, it is secondary butyl or sec -butyl : CH3 −CH2 −CH− The second isomer of butane, isobutane, can also connect in two ways, giving rise to two additional groups: If it connects at one of the three terminal carbons, it is isobutyl : 2 CH−CH2 − If it connects at the central carbon, it is tertiary butyl , tert-butyl or t -butyl : 3 C−Nomenclature According to IUPAC nomenclature , "isobutyl", "sec -butyl", and "tert -butyl" used to be allowed retained names . The latest guidance changed that: only tert -butyl is kept as preferred prefix, all other butyl-names are removed. In the convention of skeletal formulas , every line ending and line intersection specifies a carbon atom saturated with single-linked hydrogen atoms . The "R" symbol indicates any radical or other non-specific functional group .Skeletal formula Common name Preferred IUPAC name Systematic name Alternate notation n -butylbutyl butyl butan-1-yl sec -butylbutan-2-yl 1-methylpropyl butan-2-yl isobutyl 2-methylpropyl 2-methylpropyl 2-methylpropan-1-yl tert -butyltert -butyl1,1-dimethylethyl 2-methylpropan-2-yl
Butyl is the largest substituent for which trivial names are commonly used for all isomers. The butyl group's carbon that is connected to the rest of the molecule is called the RI or R-prime carbon. The prefixes sec and tert refer to the number of additional side chains connected to the first butyl carbon. The prefix "iso" means "equal" while the prefix ' n- ' stands for "normal".Example The four isomers of "butyl acetate" demonstrate these four isomeric configurations. Here, the acetate radical appears in each of the positions where the "R" symbol is used in the chart above:Etymology Alkyl radicals are often considered as a series , a progression sequenced by the number of carbon atoms involved. In that progression, Butyl is the fourth, and the last to be named for its history. The word "butyl" is derived from butyric acid , a four-carbon carboxylic acid found in rancid butter . The name "butyric acid" comes from Latin butyrum , butter . Subsequent alkyl radicals in the series are simply named from the Greek number that indicates the number of carbon atoms in the group: pentyl , hexyl , heptyl , etc.''tert''-Butyl effect The tert -butyl substituent is very bulky and is used in chemistry for kinetic stabilization , as are other bulky groups such as the related trimethylsilyl group . The effect of the tert -butyl group on the progress of a chemical reaction is called the tert -butyl effect, illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert -butyl substituent accelerates the reaction rate by a factor of 240. The tert -butyl effect is an example of steric hindrance .
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