Ammonium phosphate


Ammonium phosphate is an ammonium salt of orthophosphoric acid. It is a highly unstable compound with the formula 3PO4. Because of its instability, it is elusive and of no commercial value. A related "double salt", 3PO4.2HPO4 is also recognized but is too unstable for practical use. Both triammonium salts evolve ammonia. In contrast to the unstable nature of the triammonium salts, the diammonium phosphate 2HPO4 monoammonium salt H2PO4, are stable materials that are commonly used as fertilizers to provide plants with fixed nitrogen and phosphorus.

Preparation of triammonium phosphate

Triammonium phosphate can be prepared in the laboratory by treating 85% phosphoric acid with 30% ammonia solution:
3PO4 is a colorless, crystalline solid. The solid, which has the odor of ammonia, is readily soluble in water. The salt converts to diammonium hydrogen phosphate 2HPO4.