Caffeine synthase Caffeine synthase methyltransferase enzyme involved in the caffeine biosynthesis pathway . It is expressed in tea species , coffee species, and cocoa species. The enzyme catalyses the following reactions: S -adenosyl-L-methionine + theobromine S -adenosyl-L-homocysteine + caffeine + H+ S -adenosyl-L-methionine + paraxanthine S -adenosyl-L-homocysteine + caffeine + H+ 7-methylxanthine + S -adenosyl-L-methionine S -adenosyl-L-homocysteine + H+ + theobromine Camellia species irrawadiensis , ptilophylla , and sinensis ; the Coffea species arabica , and canephora ; and in Theobroma cacao
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