Caroline of Hesse-Homburg
Caroline of Hesse-Homburg was the daughter of Frederick V, Landgrave of Hesse-Homburg and his wife, Caroline of Hesse-Darmstadt. She married in 1791 to Louis Frederick II, Prince of Schwarzburg-Rudolstadt. They had seven children together. Caroline died on 20 June 1854.
Children
| Name | Birth | Death | Notes |
| Cäcilie of Schwarzburg-Rudolstadt | 17 July 1792 | 4 March 1794 | died in infancy |
| Friedrich Günther, Prince of Schwarzburg-Rudolstadt | 6 November 1793 | 28 June 1867 | married 1) Princess Auguste of Anhalt-Dessau, issue 2) Countess Helene of Reina, issue 3) Marie Schultze |
| Thekla of Schwarzburg-Rudolstadt | 23 February 1795 | 4 January 1861 | married Otto Victor, Prince of Schönburg-Waldenburg, issue |
| Caroline of Schwarzburg-Rudolstadt | 7 November 1796 | 18 December 1796 | died in infancy |
| Albert, Prince of Schwarzburg-Rudolstadt | 30 April 1798 | 26 November 1869 | married Princess Augusta of Solms-Braunfels |
| Bernhard of Schwarzburg-Rudolstadt | 23 June 1801 | 26 January 1816 | died young |
| Rudolph of Schwarzburg-Rudolstadt | 23 June 1801 | 21 July 1808 | died in infancy |