Chuck (season 4) Chuck May 13 , 2010. Having initially ordered 13 episodes, NBC ordered an additional 11 on October 19 , 2010 for a total of 24 episodes .Chuck faced individual villains: Alexei Volkoff , head of Volkoff Industries , and Volkoff's daughter, Vivian McArthur .Josh Schwartz and Chris Fedak expressed a desire to continue the series past the fourth season as early as March 2011 , when it was announced that the season finale would be titled "Chuck Versus the Cliffhanger". The episode, as the title suggests, had a cliffhanger ending leading into the fifth and final season, which was ordered on May 13, 2011.Cast and characters Main cast Reception UK BARB ratings
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