Fluoroalcohol


Fluoroalcohols are organofluorine compounds consisting of an alcohol functional group with at least one C-F bond. These compounds often have distinctive solvent properties.

Perfluoroalcohols

Most primary and secondary perfluoroalcohols are unstable, for example trifluoromethanol eliminates hydrogen fluoride, forming carbonyl fluoride. This reaction is reversible.
Stable perfluorinated alcohols include nonafluoro-tert-butyl alcohol, hexafluoroisopropanol and pentafluorophenol.

Partially fluorinated alcohols

Numerous partially fluorinated alcohols are known. Trifluoroethanol is a popular solvent. Fluorotelomer alcohols are precursors to perfluorocarboxylic acids. Pirkle's alcohol is used a chiral shift reagent in nuclear magnetic resonance spectroscopy.