Gas electron diffraction is one of the applications of electron diffraction techniques. The target of this method is the determination of the structure of gaseous molecules i.e. the geometrical arrangement of the atoms from which a molecule is built up. GED is one of two experimental methods to determine the structure of free molecules, undistorted by intermolecular forces, which are omnipresent in the solid and liquid state. The detremination of accurate molecular structures by GED studies are fundamental for a understanding of structural chemistry.
Introduction
Diffraction occurs because the wavelength of electrons accelerated by a potential of a few thousand volts is of the same order of magnitude as internuclear distances in molecules. The principle is the same as that of other electron diffraction methods such as LEED and RHEED, but the obtainable diffraction pattern is considerably weaker than those of LEED and RHEED because the density of the target is about one thousand times smaller. Since the orientation of the target molecules relative to the electron beams is random, the internuclear distance information obtained is one-dimensional. Thus only relatively simple molecules can be completely structurally characterized by electron diffraction in the gas phase. It is possible to combine information obtained from other sources, such as rotational spectra, NMR spectroscopy or high-quality quantum-mechanical calculations with electron diffraction data, if the latter are not sufficient to determine the molecule's structure completely. The total scattering intensity in GED is given as a function of the momentum transfer, which is defined as the difference between the wave vector of the incidentelectron beam and that of the scattered electron beam and has the reciprocal dimension of length. The total scattering intensity is composed of two parts: the atomic scattering intensity and the molecular scattering intensity. The former decreases monotonically and contains no information about the molecular structure. The latter has sinusoidal modulations as a result of the interference of the scatteringspherical waves generated by the scattering from the atoms included in the target molecule. The interferences reflect the distributions of the atoms composing the molecules, so the molecular structure is determined from this part.
Theory
GED can be described by scattering theory. The outcome if applied to gases with randomly oriented molecules is provided here in short: Scattering occurs at each individual atom, but also at pairs , or triples , of atoms. is the scattering variable or change of electron momentum and its absolute value defined as , with being the electron wavelength defined above and being the scattering angle The above mentionend contributions of scattering add up to the total scattering : , whereby is known. The most interesting contribution is the molecular scattering, because it contains information about the distance between all pairs of atoms in a molecule with being the parameter of main interest: the atomic distance between two atoms, being the mean square amplitude of vibration between the two atoms, the anharmonicity constant, and is a phase factor which becomes important if a pair of atoms with very different nuclear charge is involved. The first part is similar to the atomic scattering, but contains two scattering factors of the involved atoms. Summation is performed over all atom pairs. is negligible in most cases and not described here in more detail and is mostly determined by fitting and subtracting smooth functions to account for the background contribution. So it is the molecular scattering intensity that is of interest, and this is obtained by calculation all other contributions and subtracting them from the experimentally measured total scattering function.
Results
Some selected examples of important contributions to the structural chemistry of molecules are provided here:
