Because he was deaf, as the result of a childhood operation, he renounced his rights to the Spanish throne for himself and his descendants on 21 June/23 June 1933. He was then granted the title "Duke of Segovia" by King Alfonso XIII. After his father's death in 1941, he proclaimed himself the senior legitimate male heir of the House of Capet, heir to the French throne, and head of the House of Bourbon. He then took the title of "Duke of Anjou" and became, in the opinion of French legitimists, the de jureking of France as "Henri VI", though to a minority as "Jacques II". In 1921, he became the 1,153rd Knight of the Order of the Golden Fleece and Knight with Collar of the Order of Charles III and Grand Cross of the Order of Isabella the Catholic both in 1925. Later in 1941, following the death of his father and his ascendance to the title of King of France, Jaime adopted the Order of the Holy Spirit as his own by his right to the French Throne. , 1927
Marriage and issue
On 4 March 1935, in Rome, Jaime married Victoire Jeanne Emmanuelle Joséphine Pierre Marie de Dampierre, daughter of Roger de Dampierre, 2nd Duque de San Lorenzo Nuovo, Vicomte de Dampierre and of Donna Vittoria Ruspoli, daughter of Emanuele Ruspoli, 1st Principe di Poggio Suasa, and his third wife, English American Josephine Mary Curtis. Don Jaime and Donna Emanuela had two sons, named after Jaime's hemophiliac brothers, Alfonso and Gonzalo:
Gonzalo, Duke of Aquitaine ; he married, María Carmen Harto Montealegre on 18 April 1983. He remarried María de las Mercedes Licer García on 25 June 1984 and they were divorced on 31 January 1989. He remarried again Emanuela Maria Pratolongo on 30 June 1984 and they were separated on 7 March 1986. Gonzalo and Emanuela were also married in a religious ceremony on 17 September 1992. He has an illegitimate daughter and five grandsons.
Don Jaime and Emmanuelle de Dampierre divorced on 6 May 1947 in Bucharest and, on 3 August 1949 in Innsbruck, Don Jaime remarried civilly to divorced singer Charlotte Luise Auguste Tiedemann, daughter of Otto Eugen Tiedemann and wife Luise Amalia Klein. In the eyes of the Roman Catholic Church and of the French legitimists, Emmanuelle de Dampierre remained always his wife. The second marriage produced no children. His first wife remarried in Vienna, on 21 November 1949, to Antonio Sozzani, son of Cesare Sozzani and wife Cristina Alemani, without issue.
Renunciation
On 6 December 1949, Don Jaime retracted his renunciation of the throne of Spain. On 3 May 1964, he took the title "Duke of Madrid" as head of a Carlist branch of the Spanish succession. On 19 July 1969, Don Jaime definitively renounced the Spanish succession in favour of his nephew, the future King Juan Carlos I of Spain, at the request of his elder son, Alfonso de Borbón. Don Jaime died in St. Gall Cantonal Hospital in Switzerland on 20 March 1975. He is buried at the Royal Monastery of San Lorenzo de El Escorial.