| Name | Date | Function |
| The King Grand-Master and Founder | 1832 | By Law of 11.07.1832 |
| King Louis-Philippe | 1833 | Wedding gift to his Father-in-Law |
| The Duke of Orleans | 1833 | Wedding gift to his Brother in law |
| The Duke of Nemours | 1833 | Wedding gift to his Brother in law |
| The 2nd Count of Flahaut | 1833 | French Ambassador to the Court of St James's |
| Horace-François Sébastiani de La Porta | 1833 | French Minister of Foreign Affairs |
| 1st Duke of Dalmatia | 1833 | 10th Prime Minister of France |
| The Count of Lobau | 1833 | Marshal of France |
| The 1st Count Gérard | 1833 | 11th Prime Minister of France |
| Gabriel Neigre | 1833 | |
| The Duke of Pasquier | 1833 | president of the Chamber of Peers |
| The Baron Saint-Cyr Nugues | 1833 | |
| The Earl of Durham | 1833 | Lord Privy Seal |
| François-Nicolas-Benoît Haxo | 1833 | French Army general |
| The Duke of Choiseul-Stainville | 1833 | Governor of the Louvre Palace |
| The 3rd Duke of Broglie | 1833 | Pair of France |
| Pedro II of Brazil | 1835 | |
| Ernest I of Saxe-Coburg and Gotha | 1835 | Reigning Duke |
| Ferdinand of Saxe-Coburg and Gotha | 1835 | Brother of the King |
| Ferdinand II of Portugal | 1835 | |
| Baron Gaspard Gourgaud | 1837 | French General |
| The 1st Count of Bonfim | 1838 | 12th Prime Minister of Portugal |
| Prosper Louis, 7th Duke of Arenberg | 1838 | |
| Eugène, 8th Prince of Ligne | 1838 | President of the Senate |
| Albert of Saxe-Coburg and Gotha | 1839 | Wedding gift to the Nephew of the King |
| Henri Count of Merode, Marquess of Westerloo | 1839 | ambassador |
| Bernard Pierre Magnan | 1839 | Marshal of France |
| Ludwig I of Bavaria | 1840 | King of Bavaria |
| Charles Albert, King of Sardinia | 1840 | |
| Mgr.Luigi Lambruschini | 1840 | Cardinal Secretary of State |
| The Duke of Saxe-Meinigen | 1840 | |
| Georg of Saxe-Meiningen | 1840 | Heretier Duke of Saxe |
| The Duke of Saxe-Altenburg | 1840 | Duke of Saxe-Altenburg |
| The Duke of Württemberg | 1841 | |
| Otto of Greece | 1841 | King of Greece |
| The Duke of Aumale | 1842 | Brother in Law |
| The Prince of Joinville | 1842 | Brother in Law |
| The Grand Duke of Baden | 1843 | |
| King Frederick Augustus II | 1843 | King of Saxony |
| Louis, prince of Baden | 1843 | Crown prince |
| King Christian VIII | 1843 | King of Denmark |
| The Grand Duke of Oldenburg | 1844 | |
| Prince August of Saxe-Coburg and Gotha | 1844 | |
| The Grand Duke of Tuscany | 1844 | |
| The Duke of Montpensier | 1844 | Brother in Law |
| Emmanuel, Count of Mensdorff-Pouilly | 1845 | brother-in-law of the King |
| Archduke John of Austria | 1845 | Imperial regent |
| The Elector of Hesse | 1846 | |
| Mgr. Pecci. | 1846 | Nonce Apostolique |
| Baron Louis Atthalin | 1847 | ADC of King Louis |
| King Charles XV of Sweden | 1847 | |
| King Ferdinand II | 1847 | King of the Two Sicilies |
| The Duke of Skåne | 1849 | Crown Prince |
| William III | 1849 | King of the Netherlands |
| Emperor Franz Joseph | 1849 | Emperor of Austria |
| King Oscar I | 1849 | King of Sweden |
| King Maximilan II | 1850 | King of Bavaria |
| King Frederick William IV | 1850 | King of Prussia |
| Otto Theodor von Manteuffel | 1852 | Minister |
| Maximilian, Archduke of Austria | 1853 | Wedding Gift of the King. |
| Archduke Karl Ludwig of Austria | 1853 | Wedding Gift of the king. |
| The King of Saxony | 1853 | |
| The Duke of Brabant | 1853 | 9 April |
| King George V | 1853 | King of Hannover |
| The Grand Duke of Oldenburg | 1853 | |
| Charles, Prince of Prussia | 1853 | |
| Emperor Napoleon III | 1854 | Emperor of the French |
| The Prince Imperial | 1854 | |
| The Duke of Oporto | 1854 | Futur King of Portugal |
| King Pedro V of Portugal | 1854 | King of Portugal |
| Count Charles Lanckoroński | 1855 | Imperial Lord Chamberlain |
| The king of Saxony | 1855 | |
| The Count of Flanders | 1855 | heir presumptive to the Belgian throne |
| Vély-Eddin-Rifaat-Pach | 1855 | ambassador |
| the King of Westphalia | 1855 | |
| Antonio López de Santa Anna | 1855 | President of Mexico |
| Francis, Duke of Calabria | 1855 | |
| Luigi, Count Cibrario | 1855 | Minister of the Foreign Office |
| Mehmed Fuad Pasha | 1855 | Ministers of Foreign Affairs of the Ottoman Empire |
| Mgr. Giacomo Antonelli | 1855 | Cardinal Secretary of State |
| Alexandre, Count Colonna-Walewski | 1855 | Diplomate |
| Raymond-Theodore Troplong | 1855 | President of the French Senat |
| Friedrich von Thurn und Taxis | 1855 | Imperial Lord Chamberlain |
| Baron von Budberg | 1855 | Aide-de-camp of the Tsar |
| Jean-Baptiste, 1st Count Vaillant | 1855 | Marechal of France |
| Victor Emmanuel | 1855 | King of Sardinia |
| Heinrich von Wedel | 1855 | military Governor |
| Bernard Pierre Magnan | 1855 | French Marchall |
| Count Felix de Muelenaere | 1856 | 3rd Prime Minister of Belgium |
| Baron Étienne Constantin de Gerlache | 1856 | 1st President of the Court of Cassation |
| The Count of Theux de Meylandt | 1856 | 5th Prime Minister of Belgium |
| Oscar, Duke of Östergötland | 1856 | |
| Albrecht, Duke of Teschen | 1856 | |
| Heinrich LXVII, prince of Reuss | 1856 | |
| Alexander II of Russia | 1856 | |
| Joseph, 17th Prince of Chimay | 1856 | diplomat |
| Count Félix de Mérode | 1857 | defence minister of Belgium |
| The Duke of Loulé | 1857 | President of the Council |
| Grand Duke Nicholas of Russia | 1857 | |
| Anatole de Montesquiou-Fezensac | 1857 | |
| The 2nd Marquess of Rumigny | 1857 | Diplomate of the French King |
| Baron Pierre de Schiervel | 1857 | President of the Senate |
| Alphonse O'Sullivan de Grass | 1859 | Ambassador |
| Henri de Liem | 1859 | ADC of the King |
| Paul Devaux | | Promotor of King Leopold I |
| Mathieu Leclercq | | Minister of justice |
| The Count de Castellane | 1859 | Marshals of France |
| Name | Year | Function |
| Emperor Alexander III | 1865 | Emperor of All the Russias |
| Henri de Brouckère | 1866 | Minister |
| Viscount Charles Vilain XIIII | 1866 | Minister |
| Amadeo, Prince of Asturia | 1866 | Crown Prince of Spain |
| Barthélémy du Mortier | 1870 | botanist and Minister of State |
| Prince Arthur, Duke of Connaught and Strathearn | 1873 | Governor General of Canada |
| Naser al-Din Shah Qajar | 1873 | King of Persia |
| Archduke Rainer | 1874 | President of the Expo Vienna |
| Prince Philipp of Saxe-Coburg and Gotha | 1874 | Wedding gift to his Son in law |
| Baron Alfred von Fabrice | 1874 | Diplomate of Saxe |
| The Duke of Magenta | 1874 | President of France |
| Hüseyin Avni Pasha | 1874 | Grand Vizier of the Ottoman Empire |
| António Cardoso Avelino | 1874 | Minister of Portugal |
| BaronJomini | 1874 | Russian Diplomate, President of the congress in Brussels |
| Prince Charles III | 1874 | Sovereign of Monaco |
| Edouard d'Huart | 1878 | Minister of Finance |
| Mathieu Brialmont | 1878 | |
| Count Bloudoff | 1878 | Ambassador of the Tsar. |
| Bohuslav, Count Chotek | 1878 | Ambassador of the Emperor. |
| Rafael Carlos Merry del Val | 1878 | Ambassador to the King of Spain. |
| Mgr. Vincenzo Vannutelli | 1878 | Cardinal, Nonce Apostolique. |
| von Brandenburg | 1878 | Ambassador to the Emperor. |
| Charles Duchatel | 1878 | Ambassador to the French Republic. |
| Archduke Rudolf | 1880 | Wedding gift. |
| Walthère Frère-Orban | 1881 | Prime Minister |
| Louis Gallait | 1881 | Painter |
| Jules Malou | 1882 | Minister |
| Count Edmond de Sélys Longchamps | 1882 | President of Senate |
| the Duke of Clarence | 1885 | Cousin, Once removed |
| Prince Baudouin | 1887 | Heir to the Belgian Throne |
| baron Auguste Lambermont | 1888 | Minister of State |
| Henry Morton Stanley | 1890 | Royal Explorer of Congo. |
| Prince Karl Anton of Hohenzollern | 1894 | Nephew |
| Friedrich Krafft Graf von Crailsheim | 1894 | Foreign Minister of Bavaria |
| Auguste Beernaert | 1894 | Prime Minister. |
| François-Auguste Gevaert | 1896 | Composer |
| Christian X | 1897 | King of Denmark |
| Prince Valdemar | 1897 | |
| Prince Svasti Sobhana | 1897 | Prince of Siam |
| Prince Itō Hirobumi | 1897 | Minister |
| Prince Rupprecht | 1897 | Crown Prince of Bavaria |
| the Duke of Schleswig-Holstein | 1898 | Wedding Gift of the King |
| Queen Wilhelmina of the Netherlands | 1898 | Queen of the Netherlands |
| Queen Emma of the Netherlands | 1898 | Queen Mother |
| Émile Loubet | 1900 | President of France |
| Prince Kan'in Kotohito | 1900 | Chief of the Imperial Japanese Army General Staff |
| Duke Ludwig Wilhelm in Bavaria | 1900 | Wedding gift |
| Prince Arnulf of Bavaria | 1900 | Wedding gift |
| Karl Theodor, Duke in Bavaria | 1900 | Wedding gift |
| Ludwig III of Bavaria | 1900 | Wedding gift |
| Luitpold, Prince Regent of Bavaria | 1900 | Wedding gift |
| Adolf von Auer | 1900 | Member of the Bavarian Chamber - Royal Wedding Gift |
| Jules von Auer | 1900 | President of the Regency- Royal Wedding Gift |
| Gustav zu Castell-Castell | 1900 | Grand Master of the Royal Court - Royal Wedding Gift |
| Afons von Lerchenfeld | 1900 | Aide de Camp of the Regent - Royal Wedding Gift |
| Karl von Perfall | 1900 | Intendant of the Court - Royal Wedding Gift |
| Albert von Seinsheim | 1900 | Grand Marshall of the Court - Royal Wedding Gift |
| Franz Joseph von Stein | 1900 | Archbishop, Royal Wedding Gift |
| Rudolphe von der Tann | 1900 | Ambassador of the Regent, Royal Wedding Gift |
| Carl von Wolfskeel von Reichenberg | 1900 | Grand Eqquiery of the Regent Royal Wedding Gift |
| Ritter von Xylander | 1900 | ADC of Leopold II, Royal Wedding Gift |
| Theophile Delclassé | 1900 | Minister |
| Cardinal Goossens | 1900 | Cardinal |
| Gojong of Korea | 1901 | Emperor of Korea |
| Alfonso XIII | 1902 | King of Spain |
| the Queen of Spain | 1902 | |
| Cardinal Granito di Belmonte | 1904 | Nonce Apostolique |
| count of Wallwitz | 1904 | Ambassador of the German Emperor |
| Sunjong of Korea | 1904 | Imperial Crown Prince |
| the Duke of Saxe-Coburg and Gotha | 1905 | Wedding gift |
| Mgr. Merry del val | 1906 | Cardinal |
| Count Kiyoura Keigo | 1906 | 23rd Prime Minister of Japan |
| Haakon VII | 1906 | King of Norway |
| Tōgō Heihachirō | 1907 | Japanese Marshal-Admiral |
| Count Charles Woeste | Leopold II | Minister |
| Baron Jules-Joseph d'Anethan | Leopold II | Minister |
| Count Paul de Smet de Naeyer | Leopold II | Minister |
| Jules Greindl | Leopold II | Minister Of state |
| Count Charles John d'Oultremont | Leopold II | Marschall to the Royal Court |
| Baron Auguste Goffinet | Leopold II | Grand Master of the Imperial Household of Empress Charlotte |
