List of heads of missions from the Dominican Republic
This is a list of current Heads of Dominican Republic Missions abroad. It is up to date as of June 2020.
Resident Heads of Missions
| Mission | Location | Type | Head of Mission | Position | List |
| Saint John's | Embassy | Raquel Jacobo | Ambassador | List | |
| Vienna | Embassy | Lourdes Victoria-Kruse | Ambassador | List | |
| Brussels | Embassy | Aníbal De Castro | Ambassador | List | |
| Brasilia | Embassy | Alejandro Arias | Ambassador | List | |
| Ottawa | Embassy | Pedro Vergés | Ambassador | List | |
| Santiago | Embassy | Rubén Silié | Ambassador | List | |
| Beijing | Embassy | Briunny Garabito | Ambassador | List | |
| Bogotá | Embassy | José Ares | Ambassador | List | |
| San José | Embassy | Octavio Lister | Ambassador | List | |
| Havana | Embassy | Bolívar Marte | Ambassador | List | |
| Quito | Embassy | Víctor Lora | Ambassador | List | |
| Cairo | Embassy | Aquiles Ledesma | Ambassador | List | |
| San Salvador | Embassy | Fernando Pérez | Ambassador | List | |
| Paris | Embassy | Rosa Hernández de Grullón | Ambassador | List | |
| Berlin | Embassy | Maybe Sánchez | Ambassador | List | |
| Guatemala City | Embassy | José Leger | Ambassador | List | |
| Port-au-Prince | Embassy | Alberto Despradel | Ambassador | List | |
| Vatican City | Embassy | Eunisis Vásquez | Ambassador | List | |
| Tegucigalpa | Embassy | Marino Berigüete | Ambassador | List | |
| New Delhi | Embassy | Hans Dannenberg | Ambassador | List | |
| Tel Aviv | Embassy | John Guiliani | Ambassador | List | |
| Rome | Embassy | Rafael Tejada | Ambassador | List | |
| Kingston | Embassy | Félix García | Ambassador | List | |
| Tokyo | Embassy | Héctor Domínguez | Ambassador | List | |
| Seoul | Embassy | Humberto Salazar | Ambassador | List | |
| Mexico City | Embassy | Jonny Martínez | Ambassador | List | |
| Rabat | Embassy | Fior Pichardo | Ambassador | List | |
| The Hague | Embassy | Guillermo Piña | Ambassador | List | |
| Managua | Embassy | Luis González Sánchez | Ambassador | List | |
| Panama City | Embassy | Marino Mendoza | Ambassador | List | |
 Paraguay | Asunción | Embassy | Adonaida Medina | Ambassador | List |
| Lima | Embassy | Daniel Guerrero | Ambassador | List | |
| Lisbon | Embassy | Virgilio Alcántara | Ambassador | List | |
| Doha | Embassy | Federico Cuello | Ambassador | List | |
| Pretoria | Embassy | Héctor Galván | Ambassador | List | |
| Moscow | Embassy | José Castillo | Ambassador | List | |
| Madrid | Embassy | Olivo Rodríguez | Ambassador | List | |
| Stockholm | Embassy | Laura Faxas | Ambassador | List | |
| Berne | Embassy | Julio Simón Castaños | Ambassador | List | |
| Port of Spain | Embassy | José Serulle | Ambassador | List | |
| Ankara | Embassy | Elías Serulle | Ambassador | List | |
| Dubai | Embassy | José Soto Jiménez | Ambassador | List | |
| London | Embassy | Hugo Guiliani | Ambassador | List | |
| Washington D.C. | Embassy | José Tomás Pérez | Ambassador | List | |
| Montevideo | Embassy | Luis Arias | Ambassador | List | |
| Caracas | Embassy | Mildred Guzmán | Ambassador | List |
Non-resident Heads of Missions
The Dominican Republic does not maintain a full embassy in a number of countries. In each of these cases, the heads of Missions to another country, usually a neighbouring one, is concurrently accredited to the other country. In most cases, a smaller, local mission provides for emergencies, and is headed up by a lesser diplomat or a member of the local Dominican community.| Mission | Resident Country | Local Location | Local Mission | Non-Resident Head of Mission | Local Position |
| Algeria | N/A | N/A | Aquiles Ledesma | Ambassador to Egypt | |
 Andorra | Spain | N/A | N/A | Olivo Rodríguez | Ambassador to Spain |
| United Kingdom | N/A | N/A | Hugo Guiliani | Ambassador to the United Kingdom | |
| Venezuela | N/A | Honorary Consulate | Mildred Guzmán | Ambassador to Venezuela | |
 Belize | Honduras | N/A | N/A | Marino Berigüete | Ambassador to Honduras |
| Peru | La Paz | Honorary General-Consulate | Daniel Guerrero | Ambassador to Peru | |
| Austria | Sofia | N/A | Lourdes Victoria-Kruse | Ambassador to Austria | |
 Cyprus | Israel | N/A | N/A | John Guiliani | Ambassador to Israel |
| Belgium | Prague | N/A | Aníbal De Castro | Ambassador to Belgium | |
| Sweden | Copenhagen | Consulate | Laura Faxas | Ambassador to Sweden | |
| Sweden | Helsinki | Honorary Consulate | Laura Faxas | Ambassador to Sweden | |
| Venezuela | N/A | N/A | Mildred Guzmán | Ambassador to Venezuela | |
| United Kingdom | N/A | N/A | Hugo Guiliani | Ambassador to the United Kingdom | |
| India | N/A | N/A | Hans Dannenberg | Ambassador to India | |
| Belgium | N/A | N/A | Aníbal De Castro | Ambassador to Belgium | |
 Philippines | India | N/A | N/A | Hans Dannenberg | Ambassador to India |
 Monaco | Monaco | Montecarlo | Honorary Consulate | Rosa Hernández de Grullón | Ambassador to France |
 Mauritius | India | N/A | N/A | Hans Dannenberg | Ambassador to India |
| Palestine | N/A | N/A | Aquiles Ledesma | Ambassador to Egypt | |
 Poland | Belgium | Warsaw | N/A | Aníbal De Castro | Ambassador to Belgium |
 Romania | Italy | Bucharest | Honorary Consulate | Rafael Tejada | Ambassador to Italy |
| Poland | Belgium | Warsaw | N/A | Aníbal De Castro | Ambassador to Belgium |
 Serbia | Austria | Belgrade | N/A | Lourdes Victoria-Kruse | Ambassador to Austria |
 Singapore | N/A | N/A | N/A | Héctor Domínguez | Ambassador to Japan |
 Suriname | Venezuela | N/A | N/A | Mildred Guzmán | Ambassador to Venezuela |
 Thailand | India | Bangkok | Honorary General-Consulate | Hans Dannenberg | Ambassador to India |
 Vietnam | India | N/A | N/A | Hans Dannenberg | Ambassador to India |
Heads of Missions to non-sovereign territories
| Mission | Location | Type | Head of Mission | Position | List |
 Hong Kong, China SAR | Hong Kong | N/A | Mirna Pichardo | N/A | - |
Heads of Missions to International Organisations
| Mission | Location | Head of Mission | Position | List |
 European Union | Brussels | Aníbal De Castro | Ambassador, Permanent Representative | |
| Organization of American States | Washington, D.C. | Josué Fiallo | Ambassador, Permanent Representative | |
 United Nations in New York | New York City | Francisco Cortorreal | Ambassador, Permanent Representative | |
| United Nations in New York | New York City | José Singer | Ambassador in Special Mission to the Security Council | |
| United Nations in Geneva | Geneva | Francisco Caraballo | Ambassador, Permanent Representative to WHO, ILO & other UN agencies | |
| United Nations in Geneva | Geneva | Katrina Naut | Ambassador, Permanent Representative to WTO | |
| United Nations in Paris | Paris | José Antonio Rodríguez | Ambassador, Permanent Representative to UNESCO | |
| United Nations in Rome | Rome | Mario Arvelo | Ambassador, Permanent Representative to FAO, IFAD & WFP | |
| United Nations in Vienna | Vienna | Lourdes Victoria-Kruse | Ambassador, Permanent Representative |