Melem


In chemistry, melem is a compound with formula ; specifically, 2,5,8-triamino-heptazine or 2,5,8-triamino-tri-s-triazine, whose molecule can be described as that of heptazine with the three hydrogen atoms replaced by amino groups. It is a white crystalline solid.

Preparation

Melem can be prepared by thermal decomposition of various C−N−H compounds, such as melamine C3N33, dicyandiamide H4C2N4, ammonium dicyanamide NH4, cyanamide H2CN2, at 400 to 450 °C.

Structure and properties

Crystal structure

Melem crystallizes in the group P21/c, with parameters a = 739.92 pm, b = 865.28 pm, c = 1338.16 pm, β = 99.912°, and Z = 4. The almost-panar molecules are arranged in parallel layers spaced 327 pm apart. The molecule is in the triamino form, rather than one of the possible tautomers.

Thermal decomposition

When heated above 560, melem transforms into a graphite-like C−N material.

Melemium cations

Melem accepts up to three protons yielding cations called melemium. Some salts described in the literature are melemium sulfate, • 2, melemium perchlorate, •, melemium hydrogensulfate and two melemium methylsulfonates • and •. The protons can be inserted in any of the six outer nitrogen atoms of the heptazine core, yielding many tautomers of apparently similar energies.