Meteoric iron


Meteoric iron, sometimes meteoritic iron, is a native metal and early-universe protoplanetary-disk remnant found in meteorites and made from the elements iron and nickel mainly in the form of the mineral phases kamacite and taenite. Meteoric iron makes up the bulk of iron meteorites but is also found in other meteorites. Apart from minor amounts of telluric iron, meteoric iron is the only naturally occurring native metal of the element iron on the Earth's surface.

Mineralogy

The bulk of meteoric iron consists of taenite and kamacite. Taenite is a face centered cubic and kamacite a body centered cubic iron-nickel-alloy.
Meteoric iron can be distinguished from telluric iron by its microstructure and perhaps by its chemical composition also, since meteoritic iron contains more nickel and less carbon.
Trace amounts of gallium and germanium in meteoric iron can be used to distinguish different meteorite types. The meteoric iron in stony iron meteorites is identical to the "gallium-germanium group" of the iron meteorites.
MineralFormulaNickel Crystal structureNotes & references
AntitaeniteγLow Spin-20–40face centered cubicOnly approved as a variety of taenite by the IMA
Kamaciteα-; Fe0+0.9Ni0.15–10body centered cubicSame structure as ferrite
Taeniteγ-20–65face centered cubicSame structure as austenite
Tetrataenite48–57tetragonal

Structures

Meteoric iron forms a few different structures that can be seen by etching or in thin sections of meteorites. The Widmanstätten pattern forms when meteoric iron cools and kamacite is exsolved from taenite in the form of lamellas. Plessite is a more fine-grained intergrowth of the two minerals in between the lamella of the Widmanstätten pattern. Neumann lines are fine lines running through kamacite crystals that form through impact-related deformation.

Cultural and historical usage

Before the advent of iron smelting, meteoric iron was the only source of iron metal apart from minor amounts of telluric iron. Meteoric iron was already used before the beginning of the Iron Age to make cultural objects, tools and weapons.

Bronze Age

Many examples of iron working from the Bronze Age have been confirmed to be meteoritic in origin.
Even after the invention of smelting, meteoric iron was sometimes used where this technology was not available or metal was scarce. A piece of the Cranbourne meteorite was made into a horseshoe around 1854.
Today meteoritic iron is used in niche jewellery and knife production, but most of it is used for research, educational or collecting purposes.

Atmospheric phenomena

Meteoric iron also has an effect on the Earth's atmosphere. When meteorites descend through the atmosphere outer parts are ablated. Meteoric ablation is the source of many elements in the upper atmosphere. When meteoric iron is ablated it forms a free iron atom, that can react with ozone to form FeO. This FeO may be the source of the orange spectrographic bands in the spectrum of the upper atmosphere.