Mixed oxide


In chemistry, a mixed oxide is a somewhat informal name for an oxide that contains cations of more than one chemical element or cations of a single element in several states of oxidation.
The term is usually applied to solid ionic compounds that contain the oxide anion O2− and two or more element cations. Typical examples are ilmenite, a mixed oxide of iron and titanium cations, the mineral perovskite and oxides sharing the perovskite structure and garnet. The cations may be the same element in different ionization states: a notable example is magnetite Fe3O4, which contains the cations Fe2+ and Fe3+ in 1:2 ratio. Other notable examples include the ferrites, strontium titanate SrTiO3, yttrium aluminum garnet Y3Al5O12, and many more.
Sometimes the term is applied loosely to solid solutions of metal oxides rather than chemical compounds.
Lead dioxide and Lead monoxide combine to give Red Lead. Ferric oxide and Ferrous Oxide form the mixed oxide of Ferro-Ferric Oxide. This is also called as Magnetic Oxide.
Ilmenite is a mixed oxide of Ferrous Oxide and Titanium Oxide . It's Formula is FeTiO3. Another example is Strontium Titanate is a mixture of SrO and TiO2
Mixed oxides are intermediate between a metal oxide and a metal salt. Sometimes mixed oxides are the salts of weak metallic acids. Most other times they are just two different oxides that bond together strongly.
However, the term is sometimes also applied to compounds of oxygen and two or more other elements, where some or all of the oxygen atoms are covalently bound into oxoanions.; or to fine mixtures of two or more oxides. An example would be he zincates. Zinc hydroxide can react with concentrated sodium hydroxide to become sodium zincate. This contains zincate ions.
Mixed oxide minerals are plentiful in nature. Synthetic mixed oxides are components of many ceramics with remarkable properties and important advanced technological applications, such as strong magnets, fine optics, lasers, semiconductors, piezoelectrics, superconductors, catalysts, refractories, gas mantles, nuclear fuels, and more. Piezoelectric mixed oxides, in particular, are extensively used in pressure and strain gauges, microphones, ultrasound transducers, micromanipulators, delay lines, etc..