The Moppin Complex consists mostly of chloriteshist and amphibolite, but with lesser amounts of many other rock types, including metaconglomerate, phyllite, gneiss, and muscoviteschist. Feldspathic schist and banded iron formation are also present. The banded iron is of the Algoma variety, formed by local volcanism rather than in the Great Oxidation Event. Pillow lavas can be discerned at some locations and the overall composition of the chlorite schist is that of altered basalt. Major element and oxygen isotoperatios suggest the protolith was tholeiite. Exposures of amphibolite along Cow Creek are almost entirely very fine-grained hornblende and oligoclase. The complex crops out in the Tusas Mountains along a belt from American Creek to Jawbone Mountain. Its base is nowhere exposed, but it is at least a few thousand meters thick. The Moppin Complex is intruded by plutonic rocks, including the Maquinita Granodiorite, the trondjhemite of Rio Brazos, dikes and sills of the Burned Mountain Formation,, the Tusas Mountain Orthogneiss, and the Tres Piedras Orthogneiss. The Maquinita Granodiorite has a uranium-lead radiometric age of 1.755 Gya, which constrains the minimum age of the Moppin Complex. This makes the Moppin Complex one of the oldest known rock units in New Mexico. It likely correlates with the Pecos Complex of the Santa Fe Mountains and the Gold Hill Complex of the Taos Mountains The complex is overlain by the Vadito Group. The lower part of the Vadito Group contains amphibolite bodies that may be transitional with the Moppin Complex. The unit is interpreted as a portion of an island arcaccreted to the southern margin of Laurentia as part of the Yavapai Province between 1.8 and 1.755 Gya. The unit was intruded by the Tres Piedras Orthogneiss between 1.700 and 1.693 Gya as part of the transition from the Yavapai orogeny to the Mazatzal orogeny, and further deformed between 1.45 and 1.35 Gya.
The rock beds making up the Moppin Complex were originally named the Hopewell Series in by Evan Just in 1937 during an investigation of pegmatites in the Tusas Mountains. However, this name was already in use, and the unit was renamed the Moppin metavolcanic series by Fred Barker in 1958. With the recognition that the lithology was more diverse, including metasedimentary as well as metavolcanic rock, the unit was renamed as the Moppin Complex by Bauer and Williams in their sweeping revision of the stratigraphy of northern New Mexico Proterozoic rock units in 1989.