Within weeks of his commissioning, he saw action in the Walong sector in the 1962 Indo-China War. Since then he has served in the eastern sector six times, the last time being as the General officer commandingIV Corps. Vij has served as the General staff officer of an infantry division, a director in the Military Operations Directorate as a colonel and deputy director general of perspective planning as a brigadier at Army HQ in New Delhi. Vij served as the Major General General Staff at the Western Command in Chandimandir, Chandigarh and during the 1999 Kargil War, he served as the Director General Military Operations. During this time he was criticized for appearing, in his professional capacity before a group of senior BJP leaders, and briefing them. In 1999, he broke the military tradition to brief members of the Bharatiya Janata Party on operations in Kargil. when he was director general of military operations. For his services as the DGMO, he was awarded the Uttam Yudh Seva Medal. He was involved was the planning and execution of Operation Khukri – to extricate trapped Indian peacekeeping troops in Sierra Leone. The formations he has commanded include a mountain brigade involved in active counter-insurgency operations in the north east, an elite RAPID unit, the 1 Strike Corps based at Bhopal, Madhya Pradesh and the IV Corps based at Tezpur, Assam. He is also a recipient of the Param Vishisht Seva Medal. On 1 October 2000, Vij was appointed as the GOC of Southern Command at Pune and led the army's rescue efforts during the 2001 Gujarat earthquake. In October 2001, he was appointed as the Vice Chief of Army Staff at New Delhi and in January 2002, he was appointed as the 10th Colonel of the Dogra Regiment and the Dogra Scouts. He was appointed as the Chairman Chiefs of Staff Committee on 1 January 2005. He is married to Rita Vij and they have a son, Nalin, who is a software engineer in the United States. General Vij retired on 31 January 2005, after completing more than 42 years service.
Builders by name Adarsh Housing Cooperative Society have been constructing buildings in the prime government land in Mumbai. The permission for construction on this government land has been taken in name of providing the affordable accommodation to war widows and the land had been reserved for this purpose. However, many politicians, top military officials, other bureaucrats and their relatives have taken the ownership of the flats. Ashok Chavan, former chief minister of Maharashtra, resigned under pressure for his role in this scam. CBI is probing the scam. Gen N C Vij along with two other former military chiefs – General Deepak Kapoor, and Admiral Madhvendra Singh offered to give up their apartments.