The pair distribution function describes the distribution of distances between pairs of particles contained within a given volume. Mathematically, if a and b are two particles in a fluid, the pair distribution function of b with respect to a, denoted by is the probability of finding the particle b at distance from a, with a taken as the origin of coordinates.
Overview
The pair distribution function is used to describe the distribution of objects within a medium. If the medium is homogeneous, then there is an equal probability density for finding an object at any position : where is the volume of the container. On the other hand, the likelihood of finding pairs of objects at given positions is not uniform. For example, pairs of hard balls must be separated by at least the diameter of a ball. The pair distribution function is obtained by scaling the two-body probability density function by the total number of objects and the size of the container: In the common case where the number of objects in the container is large, this simplifies to give:
Simple models and general properties
The simplest possible pair distribution function assumes that all object locations are mutually independent, giving: where is the separation between a pair of objects. However, this is inaccurate in the case of hard objects as discussed above, because it does not account for the minimum separation required between objects. The hole-correction approximation provides a better model: where is the diameter of one of the objects. Although the HC approximation gives a reasonable description of sparsely packed objects, it breaks down for dense packing. This may be illustrated by considering a box completely filled by identical hard balls so that each ball touches its neighbours. In this case, every pair of balls in the box is separated by a distance of exactly where is a positive whole number. The pair distribution for a volume completely filled by hard spheres is therefore a set of Dirac delta functions of the form: Finally, it may be noted that a pair of objects which are separated by a large distance have no influence on each other's position. Therefore, In general, a pair distribution function will take a form somewhere between the sparsely packed and the densely packed models, depending on the packing density.
