Peroxynitrous acid
Peroxynitrous acid is a reactive nitrogen species. It is the conjugate acid of peroxynitrite. It has a pKa of ~6.8. It is formed in vivo from the diffusion-controlled reaction of nitrogen monoxide and superoxide. It is an isomer of nitric acid and isomerises with a rate constant of k = 1.2 s−1, a process whereby up to 5% of hydroxyl and nitrogen dioxide radicals may be formed. It oxidises and nitrates aromatic compounds in low yield. The mechanism may involve a complex between the aromatic compound and ONOOH, and a transition from the cis- to the trans-configuration of ONOOH. Peroxynitrous acid is also important in atmospheric chemistry.
