Phosphoryl group


A phosphoryl group is the chemical ion or radical: P+O32−, containing phosphorus and oxygen. It may exist in different protonation states.
The term is usually used to refer to compounds in which the phosphoryl group is attached to other atoms, e.g. phosphoryl chloride, or in the description of catalytic mechanisms. In biochemical reactions involving phosphates, a phosphoryl group is usually transferred between the substrates. A phosphoryl group should not be confused with a phosphate group.
The phosphoryl group plays the central role in phosphorylation.