After war broke out in the former Yugoslav republic of Croatia in the fall of 1991 and in Bosnia in April 1992, Arkan and his units moved to attack different territories in these countries. In Croatia, the Tigers fought in various locales in Eastern Slavonia. Serb Volunteer Guard under Arkan command massacred hundreds of people in eastern Croatia and Bosnia and Herzegovina while in the early ethnic cleansing campaigns in eastern Bosnia this unit had a major role. In autumn 1995, Arkan's troops fought in the area of Banja Luka, Sanski Most and Prijedor where they were routed. Arkan personally led most war actions, and rewarded his most efficient officers and soldiers with ranks, medals and eventually the products of the lootings. The Serb Volunteer Guard was officially disbanded in April 1996. Besides Arkan, a notable member of the Guard was his right-hand man, Colonel Nebojša Djordjević, who was murdered in late 1996. Another notable member was Milorad Ulemek, who is now serving a 40-year sentence for his involvement in the assassination of Serbia's pro-Western prime minister Zoran Đinđić in 2003.
Forcibly detaining approximately thirty non-Serb men and one woman, without food or water, in an inadequately ventilated boiler room of approximately in size.
Transporting twelve non-Serb men from Sanski Most to an isolated location in the village of Trnova, where they shot and killed eleven of the men and critically wounded the twelfth.
The rape of a Muslim woman on a bus outside the Hotel Sanus in Sanski Most.
Transporting approximately sixty-seven non-Serb men and one woman from Sanski Most, Šehovci, and Pobrijeze to an isolated location in the village of Sasina and shooting them, killing sixty-five of the captives and wounding two survivors.
Forcibly detaining approximately thirty-five non-Serb men in an inadequately ventilated boiler room of about five square metres in size, beating them, and depriving them of food and water, resulting in the deaths of two men.
In the 2008 Serbian film The Tour, a group of Serbian actors go on a tour in war-torn Bosnia. Among other factions, they meet an unnamed paramilitary unit wearing insignia similar to those of the Serb Volunteer Guard. Unit's commander is obviously based on Arkan.
In the 2012 Japanese anime Jormungand, one of the antagonists is Dragan Nikolaevich, commander of the Balkan Dragons. His looks and even his biography bear resounding resemblance to those of Arkan.
In fourteenth episode of the first season of the crime procedural , "Homo Homini Lupis", the suspect of the investigation is accused of raping a young girl. In the course of the detectives' interrogation, they identify the suspect as a former member of the volunteer guard due to a tigertattoo on his back and attempt to establish a pattern of behavior by pointing to the war crimes that occurred in Bosnia.