Twaron


Twaron is a para-aramid. It is a heat-resistant and strong synthetic fibre developed in the early 1970s by the Dutch company AKZO, division ENKA, later Akzo Industrial Fibers. The research name of the para-aramid fibre was originally Fiber X, but it was soon called Arenka. Although the Dutch para-aramid fiber was developed only a little later than DuPont's Kevlar, introduction of Twaron as a commercial product came much later than Kevlar due to financial problems at the AKZO company in the 1970s.

History

This is a chronology of the development of Twaron:

Polymer preparation

Twaron is a p-phenylene terephthalamide, the simplest form of the AABB para polyaramide. PpPTA is a product of p-phenylene diamine and terephthaloyl dichloride. To dissolve the aromatic polymer Twaron used a co-solvent of N-methyl pyrrolidone and an ionic component to occupy the hydrogen bonds of the amide groups. The invention of this specific process was done in 1974 at AKZO Research Laboratory in Arnhem by a team consisting of Leo Vollbracht, Teun Veerman and Wim Engelhard. The patent of the newly discovered process route led to a patent war between AKZO and DuPont as Dupont initially used the carcinogenic HMPT. Despite heavy research DuPont now also applies the AKZO patent for their Kevlar process and use the less hazardous NMP.

Spinning

After the production of the Twaron polymer in Delfzijl, the polymer is brought to Emmen, where fibres are produced by spinning the dissolved polymer into a solid fibre from a liquid chemical blend. Polymer solvent for spinning PPTA is generally 100% anhydrous sulfuric acid. The polymer is dissolved by mixing frozen sulfuric acid in powder form with the polymer in powder form and gently heating the mixture. This process, which differs from the more difficult DuPont process, was invented by Henri Lammers and patented by AKZO.

Industrial uses

Twaron is a para-aramid and is used in automotive, construction, sport, aerospace, military and industry applications, e.g., "bullet-proof" body armor, fabric, and as an asbestos substitute.
;Protective gear : flame-resistant clothing, protective clothing and helmets, cut-fast or heat-hardy gloves, sporting goods, textiles, ballistic vests
;Composites: composite materials, technical paper, asbestos replacement, hot air filtration, sailcloth, speaker woofers, boat hull material, fiber reinforced concrete, drumheads
;Automotive: brake pads, turbo hoses, V-belts and Timing belts, tires that incorporate Sulfron, mechanical rubber goods reinforcement
;Linear tension: optical fiber cables, ropes, wire ropes, electrical cables, umbilical cables, electrical mechanical cable, reinforced thermoplastic pipes