Valentine de Riquet de Caraman-Chimay
Countess Valentine de Riquet de Caraman was a Belgian princess. She was the daughter of Joseph de Riquet de Caraman-Chimay and Émilie Pellapra. Her first marriage was to prince Paul de Bauffremont on 13 April 1861, but this ended in divorce in 1875 - she gained custody of her two children and later the same year married Georges Bibescu, son of Gheorghe Bibescu, with whom she had three more children - Georges, Nadège and Georges-Valentin.