The name xenotime is from the Greek words κενός vain and τιμή honor, akin to "vainglory". It was coined by French mineralogist François Sulpice Beudant as a rebuke of another scientist, Swedish chemist Jöns Jacob Berzelius, for the latter's premature claim to have found in the mineral a new chemical element. The criticism was blunted, as over time "kenotime" was misread and misprinted "xenotime". Xenotime was first described for an occurrence in Vest-Agder, Norway in 1824.
Properties
Crystallising in the tetragonal crystal system, xenotime is typically translucent to opaque in shades of brown to brownish yellow but also reddish to greenish brown and gray. Xenotime has a variable habit: It may be prismatic with dipyramidal terminations, in radial or granular aggregates, or rosettes. A soft mineral, xenotime is—in comparison to most other translucent minerals—fairly dense, with a specific gravity between 4.4-5.1. Its lustre, which may be vitreous to resinous, together with its crystal system, may lead to a confusion with zircon, the latter having a similar crystal structure and with which xenotime may sometimes occur. Xenotime has two directions of perfect prismatic cleavage and its fracture is uneven to irregular. It is considered brittle and its streak is white. The refractive index of xenotime is 1.720-1.815 with a birefringence of 0.095. Xenotime is dichroic with pink, yellow or yellowish brown seen in the extraordinary ray and brownish yellow, grayish brown or greenish brown seen in the ordinary ray. There is no reaction under ultraviolet light. While xenotime may contain significant amounts of thorium or uranium, the mineral does not undergo metamictization like sphene or zircon would.
Occurrence
Occurring as a minoraccessory mineral, xenotime is found in pegmatites and other igneous rocks, as well as gneisses rich in mica and quartz. Associated minerals include biotite and other micas, chlorite group minerals, quartz, zircon, certain feldspars, analcime, anatase, brookite, rutile, siderite and apatite. Xenotime is also known to be diagenetic: It may form as minute grains or as extremely thin coatings on detrital zircon grains in siliciclastic sedimentary rocks. The importance of these diagenetic xenotime deposits in the radiometric dating of sedimentary rocks is only beginning to be realised. Discovered in 1824, xenotime's type locality is Hidra, Flekkefjord, Vest-Agder, Norway. Other notable localities include: Arendal and Tvedestrand, Norway; Novo Horizonte, São Paulo, Novo Horizonte, Bahia and Minas Gerais, Brazil; Madagascar and California, Colorado, Georgia, North Carolina and New Hampshire, United States. A new discovery of gemmy, colour change xenotime has been reported from Afghanistan and been found in Pakistan. North of Mount Funabuse in Gifu Prefecture, Japan, a notable basaltic rock is quarried at a hill called Maru-Yama: crystals of xenotime and zircon arranged in a radiating, flower-like pattern are visible in polished slices of the rock, which is known as chrysanthemum stone. This stone is widely appreciated in Japan for its ornamental value. Small tonnages of xenotime sand are recovered in association with Malaysian tin mining, etc. and are processed commercially. The lanthanide content is typical of "yttrium earth" minerals and runs about two-thirds yttrium, with the remainder being mostly the heavy lanthanides, where the even-numbered lanthanides each being present at about the 5% level, and the odd-numbered lanthanides each being present at about the 1% level. Dysprosium is usually the most abundant of the even-numbered heavies, and holmium is the most abundant of the odd-numbered heavies. The lightest lanthanides are generally better represented in monazite while the heaviest lanthanides are in xenotime.
