Zirconyl chloride Zirconyl chloride is the inorganic compound with the formula of Cl 8 12 , more commonly written ZrOCl2 ·8H2 O, and referred to as zirconyl chloride octahydrate. It is a white solid and is the most common water-soluble derivative of zirconium . A compound with the formula ZrOCl2 has not been characterized.The salt is produced by hydrolysis of zirconium tetrachloride or treating zirconium oxide with hydrochloric acid . It adopts a tetrameric structure, consisting of the cation 8+ . features four pairs of hydroxide bridging ligands linking four Zr 4+ centers. The chloride anions are not ligands, consistent with the high oxophilicity of Zr. The salt crystallizes as tetragonal crystals .
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