Formyl cyanide


Formyl cyanide is a simple organic molecule with formula HCOCN. It is simultaneously a nitrile and a carbonyl. Formyl cyanide is the simplest member of the acyl cyanide family. It is known to occur in space in the Sgr B2 molecular cloud.

Production

Formyl cyanide was first made by heating methoxyacetonitrile at 600 °C. Formyl cyanide can also be made by heating cinnamyloxyacetonitrile or allyloxyacetonitrile.
In molecular clouds, formation of formyl cyanide is speculated to result from formaldehyde and the cyanide radical:
In Earth's atmosphere, the pollutant acrylonitrile reacts with hydroxyl radical forming formyl cyanide, hydroperoxyl and formaldehyde:

Reactions

Formyl cyanide reacts with water to form formic acid and hydrogen cyanide.

Related

By formally substituting the hydrogen atom, cyanoformyl chloride, ClCCN, and cyanoformyl bromide, BrCCN are obtained.