List of copper alloys
Copper alloys are metal alloys that have copper as their principal component. They have high resistance against corrosion. The best known traditional types are bronze, where tin is a significant addition, and brass, using zinc instead. Both of these are imprecise terms, having both been commonly referred to as lattens in the past. Today the term copper alloy tends to be substituted, especially by museums.
Composition
The similarity in external appearance of the various alloys, along with the different combinations of elements used when making each alloy, can lead to confusion when categorizing the different compositions. There are as many as 400 different copper and copper alloy compositions loosely grouped into the categories: copper, high copper alloy, brasses, bronzes, copper nickels, copper-nickel-zinc, leaded copper, and special alloys. The following table lists the principal alloying element for four of the more common types used in modern industry, along with the name for each type. Historical types, such as those that characterize the Bronze Age, are vaguer as the mixtures were generally variable.Family | Principal alloying element | UNS numbers |
Copper alloys, brass | Zinc | C1xxxx-C4xxxx,C66400-C69800 |
Phosphor bronze | Tin | C5xxxx |
Aluminium bronzes | Aluminium | C60600-C64200 |
Silicon bronzes | Silicon | C64700-C66100 |
Cupronickel, nickel silvers | Nickel | C7xxxx |
Name | Nominal composition | Form and condition | Yield strength | Tensile strength | Elongation in 2 inches | Hardness | Comments |
Copper | Cu 99.9 | Annealed | 10 | 32 | 45 | 42 | Electrical equipment, roofing, screens |
Cold-drawn | 40 | 45 | 15 | 90 | |||
Cold-rolled | 40 | 46 | 5 | 100 | |||
Gilding metal | Cu 95.0, Zn 5.0 | Cold-rolled | 50 | 56 | 5 | 114 | Coins, bullet jackets |
Cartridge brass | Cu 70.0, Zn 30.0 | Cold-rolled | 63 | 76 | 8 | 155 | Good for cold-working; radiators, hardware, electrical, drawn cartridge cases. |
Phosphor bronze | Cu 89.75, Sn 10.0, P 0.25 | Spring temper | — | 122 | 4 | 241 | High fatigue-strength and spring qualities |
Yellow or High brass | Cu 65.0, Zn 35.0 | Annealed | 18 | 48 | 60 | 55 | Good corrosion resistance |
Cold-drawn | 55 | 70 | 15 | 115 | |||
Cold-rolled | 60 | 74 | 10 | 180 | |||
Manganese bronze | Cu 58.5, Zn 39.2, Fe 1.0, Sn 1.0, Mn 0.3 | Annealed | 30 | 60 | 30 | 95 | Forgings |
Cold-drawn | 50 | 80 | 20 | 180 | |||
Naval brass | Cu 60.0, Zn 39.25, Sn 0.75 | Annealed | 22 | 56 | 40 | 90 | Resistance to salt corrosion |
Cold-drawn | 40 | 65 | 35 | 150 | |||
Muntz metal | Cu 60.0, Zn 40.0 | Annealed | 20 | 54 | 45 | 80 | Condensor tubes |
Aluminium bronze | Cu 92.0, Al 8.0 | Annealed | 25 | 70 | 60 | 80 | — |
Hard | 65 | 105 | 7 | 210 | |||
Beryllium copper | Cu 97.75, Be 2.0, Co or Ni 0.25 | Annealed, solution-treated | 32 | 70 | 45 | B60 | Electrical, valves, pumps, oilfield tools, aerospace landing gears, robotic welding, mold making |
Cold-rolled | 104 | 110 | 5 | B81 | |||
Free-cutting brass | Cu 62.0, Zn 35.5, Pb 2.5 | Cold-drawn | 44 | 70 | 18 | B80 | Screws, nuts, gears, keys |
Nickel silver | Cu 65.0, Zn 17.0, Ni 18.0 | Annealed | 25 | 58 | 40 | 70 | Hardware |
Cold-rolled | 70 | 85 | 4 | 170 | |||
Nickel silver | Cu 76.5, Ni 12.5, Pb 9.0, Sn 2.0 | Cast | 18 | 35 | 15 | 55 | Easy to machine; ornaments, plumbing |
Cupronickel | Cu 88.35, Ni 10.0, Fe 1.25, Mn 0.4 | Annealed | 22 | 44 | 45 | – | Condensor, salt-water pipes |
Cold-drawn tube | 57 | 60 | 15 | – | |||
Cupronickel | Cu 70.0, Ni 30.0 | Wrought | – | – | – | – | Heat-exchange equipment, valves |
Ounce metal Copper alloy C83600 | Cu 85.0, Zn 5.0, Pb 5.0, Sn 5.0 | Cast | 17 | 37 | 25 | 60 | — |
Gunmetal | Varies Cu 80-90%, Zn <5%, Sn ~10%, +other elements@ <1% | - |
Family | CDA | ASTM | SAE | SAE superseded | Federal | Military |
Red brass | 833 | |||||
Red brass | 836 | B145-836 | 836 | 40 | QQ-C-390 | C-2229 Gr2 |
Red brass | 838 | B145-838 | 838 | QQ-C-390 | ||
Semi-red brass | 844 | B145-844 | QQ-C-390 | |||
Semi-red brass | 848 | B145-848 | QQ-C-390 | |||
Manganese bronze | 862 | B147-862 | 862 | 430A | QQ-C-390 | C-2229 Gr9 |
Manganese bronze | 863 | B147-863 | 863 | 430B | QQ-C-390 | C-2229 Gr8 |
Manganese bronze | 865 | B147-865 | 865 | 43 | QQ-C-390 | C-2229 Gr7 |
Tin bronze | 903 | B143-903 | 903 | 620 | QQ-C-390 | C-2229 Gr1 |
Tin bronze | 905 | B143-905 | 905 | 62 | QQ-C-390 | |
Tin bronze | 907 | 907 | 65 | |||
Leaded tin bronze | 922 | B143-922 | 922 | 622 | QQ-C-390 | B-16541 |
Leaded tin bronze | 923 | B143-923 | 923 | 621 | QQ-C-390 | C-15345 Gr10 |
Leaded tin bronze | 926 | 926 | ||||
Leaded tin bronze | 927 | 927 | 63 | |||
High-leaded tin bronze | 932 | B144-932 | 932 | 660 | QQ-C-390 | C-15345 Gr12 |
High-leaded tin bronze | 934 | QQ-C-390 | C-22229 Gr3 | |||
High-leaded tin bronze | 935 | B144-935 | 935 | 66 | QQ-C-390 | |
High-leaded tin bronze | 937 | B144-937 | 937 | 64 | QQ-C-390 | |
High-leaded tin bronze | 938 | B144-938 | 938 | 67 | QQ-C-390 | |
High-leaded tin bronze | 943 | B144-943 | 943 | QQ-C-390 | ||
Aluminium bronze | 952 | B148-952 | 952 | 68A | QQ-C-390 | C-22229 Gr5 |
Aluminium bronze | 953 | B148-953 | 953 | 68B | QQ-C-390 | |
Aluminium bronze | 954 | B148-954 | 954 | QQ-C-390 | C-15345 Gr13 | |
Aluminium bronze | 955 | B148-955 | 955 | QQ-C-390 | C-22229 Gr8 | |
Aluminium bronze | 958 | QQ-C-390 | ||||
Silicon bronze | 878 | B30 | 878 |
The following table outlines the chemical composition of various grades of copper alloys.
Brasses
A brass is an alloy of copper with zinc. Brasses are usually yellow in colour. The zinc content can vary between few % to about 40%; as long as it is kept under 15%, it does not markedly decrease corrosion resistance of copper.Brasses can be sensitive to selective leaching corrosion under certain conditions, when zinc is leached from the alloy, leaving behind a spongy copper structure.
- Nordic Gold
Bronzes
- Aluminium bronzes are alloys of copper and aluminium. The content of aluminium ranges mostly between 5% and 11%. Iron, nickel, manganese and silicon are sometimes added. They have higher strength and corrosion resistance than other bronzes, especially in marine environment, and have low reactivity to sulphur compounds. Aluminium forms a thin passivation layer on the surface of the metal.
- Bell metal
- Phosphor bronze
- Nickel bronzes, e.g. nickel silver and cupronickel
- Speculum metal
- UNS C69100
Precious metal alloys
Name | Cu | Au | Ag | Other |
Auricupride | † | † | ||
Ashtadhatu | † | † | † | Fe†, Hg†, Sn†, Zn† |
Billon | † | † | Hg† | |
Chinese silver | 58 | 2 | 17.5 Zn, 11.5 Ni, | |
Corinthian bronze | † | † | † | |
CuSil | 28 | 72 | ||
Dymalloy | 20 | 80 | C | |
Electrum, Green gold | 6-23 | 75-80 | 0-15 | 0-4 Cd |
Grey gold | † | † | Mn† | |
Guanín | 25 | 56 | 18 | |
Hepatizon | † | trace | trace | |
Niello | † | † | Pb sulfides† | |
Panchaloha | † | † | † | Fe†, Sn†, Pb†, Zn†, |
Rose, red, and pink gold | 20-50 | 50-75 | 0-5 | |
Spangold | 18-19 | 76 | 5-6 Al | |
Shakudō | 90-96 | 4-10 | ||
Shibuichi | 40-77 | 0-1 | 23-60 | |
Tibetan silver | † | † | Ni†, Sn† | |
Tumbaga | 3-97 | 3-97 | ||
White gold | † | † | Ni†, Zn† |
† amount unspecified