Triphenylcarbenium


In chemistry, triphenylcarbenium, triphenylmethyl cation, tritylium , or trityl cation is an ion with formula or, consisting of a carbon atom with a positive charge connected to three phenyl groups. It is a charged version of the triphenylmethyl radical •. The name is often abbreviated to triphenylmethyl or trityl in salts, although these names also denote the chemical group in compounds like triphenylmethyl chloride that do not contain the cation.
Triphenylcarbenium is a relatively stable carbenium ion, because the positive charge can be distributed among 10 of the carbon atoms. The cation exists in important chemical reagents and catalysts such as
This and other similar cations can be obtained as intensely colored solutions by dissolving aryl-substituted methanols in concentrated sulfuric acid.

Derivatives

Derivatives of this cation include, for example, perchlorotriphenylcarbenium.

Triarylmethane dyes

s are derivatives are stabilized version of the trityl cation. They are water-soluble and are often obtained as the chloride salts. These dyes have strong electron donor groups, often amines, at the p-positions of two or three of the aryl groups.