Given a system characterized by the action in terms of Grassmann fields, the partition function can be expressed as the path integral: where is a binary source field. By expansion in the Dyson series, one finds that is the sum of all, closed Feynman diagrams. in turn is the generating functional of the N-particle Green's function: The asserts that the effective action is the sum of all closed, connected, bare diagrams. in turn is the generating functional for the connected Green's function. As an example, the two particle connected Green's function reads: To pass to the two-particle irreducible effective action, one performs a Legendre transform of to a new binary source field. One chooses an, at this point arbitrary, convex as the source and obtains the 2PI functional, also known as Baym–Kadanoff functional: Unlike the connected case, one more step is required to obtain a generating functional from the two-particle irreducible effective action because of the presence of a non-interacting part. By subtracting it, one obtains the Luttinger–Ward functional: where is the self-energy. Along the lines of the proof of the linked-cluster theorem, one can show that this is the generating functional for the two-particle irreducible propagators.
Properties
Diagrammatically, the Luttinger–Ward functional is the sum of all closed, bold, two-particle irreducible Feynman diagrams : The diagrams are closed as they do not have any external legs, i.e., no particles going in or out of the diagram. They are “bold” because they are formulated in terms of the interacting or bold propagator rather than the non-interacting one. They are two-particle irreducible since they do not become disconnected if we sever up to two fermionic lines. The Luttinger–Ward functional is related to the grand potential of a system: is a generating functional for irreducible vertex quantities: the first functional derivativewith respect to gives the self-energy, while the second derivative gives the partially two-particle irreducible four-point vertex: While the Luttinger–Ward functional exists, it can be shown to be not unique for Hubbard-like models. In particular, the irreducible vertex functions show a set of divergencies, which causes the self-energy to bifurcate into a causal and a non-causal solution. However, by restricting the self-energy to causal solutions, one can restore uniqueness of the functional. Baym and Kadanoff showed that any diagrammatic truncation of the Luttinger–Ward functional fulfills a set of conservation laws. Approximations that are equivalent to such a truncation are therefore called conserving or -derivable. Some examples:
The GW approximation is equivalent to truncating to so-called ring diagrams: .
Dynamical mean field theory is equivalent to taking only purely local diagrams into account:, where are lattice site indices.