Sodium ferrocyanide


Sodium ferrocyanide is the sodium salt of the coordination compound of formula 4−. In its hydrous form, Na4Fe6, it is sometimes known as yellow prussiate of soda. It is a yellow crystalline solid that is soluble in water and insoluble in alcohol. The yellow color is the color of ferrocyanide anion. Despite the presence of the cyanide ligands, sodium ferrocyanide has low toxicity. The ferrocyanides are less toxic than many salts of cyanide, because they tend not to release free cyanide. However, like all ferrocyanide salt solutions, addition of an acid can result in the production of hydrogen cyanide gas, which is toxic.

Uses

When combined with iron, it converts to a deep blue pigment called Prussian blue. It is used as a stabilizer for the coating on welding rods. In the petroleum industry, it is used for removal of mercaptans.
In the EU, ferrocyanides were, as of 2018, solely authorised in two food categories as salt substitutes. Kidneys are the organ for ferrocyanide toxicity.

Production

Sodium ferrocyanide is produced industrially from hydrogen cyanide, ferrous chloride, and calcium hydroxide, the combination of which affords Ca2. A solution of this salt is then treated with sodium salts to precipitate the mixed calcium-sodium salt CaNa2, which in turn is treated with sodium carbonate to give the tetrasodium salt.